Acta Geographica Sinica ›› 2021, Vol. 76 ›› Issue (3): 713-725.doi: 10.11821/dlxb202103015
• Environment and Ecosystem Services • Previous Articles Next Articles
Received:
2020-03-14
Revised:
2021-02-28
Online:
2021-03-25
Published:
2021-05-25
Supported by:
LYU Jianshu. Source apportionment and spatial prediction of heavy metals in soils of Yantai coastal zone[J].Acta Geographica Sinica, 2021, 76(3): 713-725.
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Tab. 1
Descriptive statistics of heavy metals in soils of Yantai coastal zone (mg kg-1)
As | Cd | Co | Cr | Cu | Hg | Mn | Ni | Pb | Zn | pH | |
---|---|---|---|---|---|---|---|---|---|---|---|
最小值 | 2.2 | 0.01 | 0.6 | 7.2 | 1.1 | 0.006 | 63 | 3.6 | 16.1 | 6.9 | 4.66 |
最大值 | 99.0 | 8.27 | 45.2 | 206.6 | 302.1 | 3.210 | 1634 | 144.9 | 917.6 | 493.9 | 9.35 |
平均值 | 7.8 | 0.17 | 11.2 | 58.8 | 32.3 | 0.078 | 491 | 25.3 | 34.7 | 68.0 | 6.76 |
标准差 | 6.33 | 0.28 | 4.67 | 23.41 | 23.91 | 0.17 | 153.90 | 11.87 | 38.83 | 26.60 | 0.95 |
变异系数 | 0.82 | 1.66 | 0.42 | 0.40 | 0.74 | 2.23 | 0.31 | 0.47 | 1.12 | 0.39 | 0.14 |
偏度 | 7.69 | 23.13 | 1.17 | 1.40 | 3.56 | 9.50 | 1.61 | 2.43 | 19.05 | 4.85 | -0.05 |
峰度 | 90.04 | 647.80 | 3.94 | 5.74 | 25.28 | 126.58 | 8.22 | 16.28 | 408.44 | 64.44 | -1.07 |
K-S检验(P) | 0.000 | 0.000 | 0.002 | 0.001 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 |
山东东部土壤 重金属背景值[ | 6.3 | 0.108 | 11.0 | 56.2 | 19.6 | 0.029 | 552 | 23.5 | 25.4 | 56.1 | - |
农用地土壤污染 风险筛选值* | 30 | 0.3 | - | 200 | 100 | 2.4 | - | 100 | 120 | 250 | - |
第一类建设用地土壤污染风险筛选值 | 20 | 20 | 20 | -** | 2000 | 8 | - | 150 | 400 | - | - |
Tab. 1
Descriptive statistics of heavy metals in soils of Yantai coastal zone (mg kg-1)
As | Cd | Co | Cr | Cu | Hg | Mn | Ni | Pb | Zn | pH | |
---|---|---|---|---|---|---|---|---|---|---|---|
最小值 | 2.2 | 0.01 | 0.6 | 7.2 | 1.1 | 0.006 | 63 | 3.6 | 16.1 | 6.9 | 4.66 |
最大值 | 99.0 | 8.27 | 45.2 | 206.6 | 302.1 | 3.210 | 1634 | 144.9 | 917.6 | 493.9 | 9.35 |
平均值 | 7.8 | 0.17 | 11.2 | 58.8 | 32.3 | 0.078 | 491 | 25.3 | 34.7 | 68.0 | 6.76 |
标准差 | 6.33 | 0.28 | 4.67 | 23.41 | 23.91 | 0.17 | 153.90 | 11.87 | 38.83 | 26.60 | 0.95 |
变异系数 | 0.82 | 1.66 | 0.42 | 0.40 | 0.74 | 2.23 | 0.31 | 0.47 | 1.12 | 0.39 | 0.14 |
偏度 | 7.69 | 23.13 | 1.17 | 1.40 | 3.56 | 9.50 | 1.61 | 2.43 | 19.05 | 4.85 | -0.05 |
峰度 | 90.04 | 647.80 | 3.94 | 5.74 | 25.28 | 126.58 | 8.22 | 16.28 | 408.44 | 64.44 | -1.07 |
K-S检验(P) | 0.000 | 0.000 | 0.002 | 0.001 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 |
山东东部土壤 重金属背景值[ | 6.3 | 0.108 | 11.0 | 56.2 | 19.6 | 0.029 | 552 | 23.5 | 25.4 | 56.1 | - |
农用地土壤污染 风险筛选值* | 30 | 0.3 | - | 200 | 100 | 2.4 | - | 100 | 120 | 250 | - |
第一类建设用地土壤污染风险筛选值 | 20 | 20 | 20 | -** | 2000 | 8 | - | 150 | 400 | - | - |
Tab. 2
The results of PMF modeling of heavy metals in soils of Yantai coastal zone
模型验证 | 源成分谱(mg kg-1) | 源贡献率(%) | ||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|
R2 | 预测值/实际值 | 因子1 | 因子2 | 因子3 | 因子4 | 因子1 | 因子2 | 因子3 | 因子4 | |||
As | 1.00 | 1.00 | 6.1 | 1.0 | 0.5 | 0.1 | 79.2 | 12.6 | 6.6 | 1.5 | ||
Cd | 0.79 | 0.96 | 0.06 | 0.01 | 0.10 | 0.00 | 33.8 | 58.3 | 5.7 | 2.1 | ||
Co | 0.93 | 0.98 | 9.3 | 0.7 | 0.8 | 0.2 | 85.0 | 6.2 | 6.9 | 1.9 | ||
Cr | 0.83 | 0.98 | 47.9 | 4.6 | 3.6 | 1.3 | 83.4 | 8.1 | 6.4 | 2.2 | ||
Cu | 1.00 | 1.00 | 9.9 | 5.7 | 16.3 | 0.4 | 30.7 | 17.6 | 50.5 | 1.2 | ||
Hg | 1.00 | 0.98 | 0.010 | 0.006 | 0.003 | 0.059 | 12.7 | 8.1 | 3.5 | 75.7 | ||
Mn | 0.88 | 0.96 | 369 | 66 | 29 | 8 | 78.2 | 14.0 | 6.2 | 1.6 | ||
Ni | 0.85 | 0.96 | 20.8 | 1.3 | 1.7 | 0.5 | 85.3 | 5.5 | 6.9 | 2.3 | ||
Pb | 0.83 | 0.93 | 15.5 | 13.1 | 2.8 | 1.1 | 47.7 | 40.3 | 8.5 | 3.5 | ||
Zn | 0.63 | 0.94 | 32.6 | 23.0 | 6.8 | 1.8 | 50.8 | 35.8 | 10.6 | 2.8 |
Tab. 2
The results of PMF modeling of heavy metals in soils of Yantai coastal zone
模型验证 | 源成分谱(mg kg-1) | 源贡献率(%) | ||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|
R2 | 预测值/实际值 | 因子1 | 因子2 | 因子3 | 因子4 | 因子1 | 因子2 | 因子3 | 因子4 | |||
As | 1.00 | 1.00 | 6.1 | 1.0 | 0.5 | 0.1 | 79.2 | 12.6 | 6.6 | 1.5 | ||
Cd | 0.79 | 0.96 | 0.06 | 0.01 | 0.10 | 0.00 | 33.8 | 58.3 | 5.7 | 2.1 | ||
Co | 0.93 | 0.98 | 9.3 | 0.7 | 0.8 | 0.2 | 85.0 | 6.2 | 6.9 | 1.9 | ||
Cr | 0.83 | 0.98 | 47.9 | 4.6 | 3.6 | 1.3 | 83.4 | 8.1 | 6.4 | 2.2 | ||
Cu | 1.00 | 1.00 | 9.9 | 5.7 | 16.3 | 0.4 | 30.7 | 17.6 | 50.5 | 1.2 | ||
Hg | 1.00 | 0.98 | 0.010 | 0.006 | 0.003 | 0.059 | 12.7 | 8.1 | 3.5 | 75.7 | ||
Mn | 0.88 | 0.96 | 369 | 66 | 29 | 8 | 78.2 | 14.0 | 6.2 | 1.6 | ||
Ni | 0.85 | 0.96 | 20.8 | 1.3 | 1.7 | 0.5 | 85.3 | 5.5 | 6.9 | 2.3 | ||
Pb | 0.83 | 0.93 | 15.5 | 13.1 | 2.8 | 1.1 | 47.7 | 40.3 | 8.5 | 3.5 | ||
Zn | 0.63 | 0.94 | 32.6 | 23.0 | 6.8 | 1.8 | 50.8 | 35.8 | 10.6 | 2.8 |
Tab. 3
Parameters of variogram fitting of independent components
变量 | 模型结构 | 块金值 | 结构1 | 结构2 | 块金值/总方差 | |||
---|---|---|---|---|---|---|---|---|
基台值 | 变程(m) | 基台值 | 变程(m) | |||||
IC1 | Nugget+Spherical+Spherical | 0.31 | 0.26 | 7195 | 0.46 | 29307 | 0.30 | |
IC2 | Nugget+Spherical+Spherical | 0.38 | 0.10 | 8299 | 0.47 | 29457 | 0.40 | |
IC3 | Nugget+Spherical+Spherical | 0.46 | 0.32 | 13513 | 0.35 | 37496 | 0.41 | |
IC4 | Nugget+Spherical+Spherical | 0.25 | 0.59 | 8674 | 10.08 | 1661216 | 0.02 | |
IC5 | Nugget+Spherical | 0.68 | 0.25 | 18673 | 0.73 | |||
IC6 | Nugget+Spherical+Spherical | 0.38 | 0.30 | 7733 | 0.28 | 25534 | 0.40 | |
IC7 | Nugget+Spherical | 0.65 | 2.73 | 548386 | 0.19 | |||
IC8 | Nugget+Spherical | 0.26 | 0.88 | 19044 | 0.23 | |||
IC9 | Nugget+Spherical+Spherical | 0.50 | 0.22 | 4317 | 0.30 | 20506 | 0.49 | |
IC10 | Nugget+Spherical+Spherical | 0.55 | 0.27 | 7141 | 0.30 | 61258 | 0.49 |
Tab. 3
Parameters of variogram fitting of independent components
变量 | 模型结构 | 块金值 | 结构1 | 结构2 | 块金值/总方差 | |||
---|---|---|---|---|---|---|---|---|
基台值 | 变程(m) | 基台值 | 变程(m) | |||||
IC1 | Nugget+Spherical+Spherical | 0.31 | 0.26 | 7195 | 0.46 | 29307 | 0.30 | |
IC2 | Nugget+Spherical+Spherical | 0.38 | 0.10 | 8299 | 0.47 | 29457 | 0.40 | |
IC3 | Nugget+Spherical+Spherical | 0.46 | 0.32 | 13513 | 0.35 | 37496 | 0.41 | |
IC4 | Nugget+Spherical+Spherical | 0.25 | 0.59 | 8674 | 10.08 | 1661216 | 0.02 | |
IC5 | Nugget+Spherical | 0.68 | 0.25 | 18673 | 0.73 | |||
IC6 | Nugget+Spherical+Spherical | 0.38 | 0.30 | 7733 | 0.28 | 25534 | 0.40 | |
IC7 | Nugget+Spherical | 0.65 | 2.73 | 548386 | 0.19 | |||
IC8 | Nugget+Spherical | 0.26 | 0.88 | 19044 | 0.23 | |||
IC9 | Nugget+Spherical+Spherical | 0.50 | 0.22 | 4317 | 0.30 | 20506 | 0.49 | |
IC10 | Nugget+Spherical+Spherical | 0.55 | 0.27 | 7141 | 0.30 | 61258 | 0.49 |
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