偏远地区铅和汞的现代过程与历史记录研究综述

doi:10.11821/xb201003010

Abstract

Abstract:

Atmospheric heavy metals (especially Pb and Hg) from anthropogenic activities could be transported globally, resulting in tremendous negative effects on the environment. Therefore, such research has received increasing attention in recent decades. In order to evaluate the pollution status, to understand the global transport process, and to elucidate its biogeochemical cycle and ultimate fate, it is necessary to carry out related studies in remote areas. In this paper, the progress on the historical reconstruction of heavy metals through ice core and lake sediment, as well as modern long range transport process are summarized. Based on the discussion, the directions for future studies are also proposed. Due to the unique atmospheric circulation regime and clean environment, the Tibetan Plateau is an ideal region to monitor atmospheric environmental change and to evaluate various impacts caused by human activities. Nam Co, as one of the typical regions of the Tibetan Plateau, has obvious advantages for such research due to various environmental archives (ice core and lake sediment) available. The establishment of Nam Co Station (under the Institute of Tibetan Plateau Research, CAS) also makes it practicable to conduct long-term monitoring of the modern atmospheric properties.

Key words: remote area, lead, mercury, long range transport, Tibetan Plateau

CONG Zhiyuan1, KANG Shichang1, 2, ZHENG Wei1, ZHANG Qianggong1. Modern Process and Historical Reconstruction of Pb and Hg in Remote Areas: A Critical Review[J].Acta Geographica Sinica, 2010, 65(3): 351-360.

References

[1] UNEP. Global Mercury Assessment Report. Geneva, Switzerland, 2003.

[2] Lai S O, Holsen T M, Han Y J et al. Estimation of mercury loadings to Lake Ontario: Results from the Lake Ontario atmospheric deposition study (LOADS). Atmospheric Environment, 2007, 41(37): 8205-8218.

[3] Gbor P K, Wen D, Meng F et al. Modeling of mercury emission, transport and deposition in North America. Atmospheric Environment, 2007, 41(6): 1135-1149.

[4] Pan L, Carmichael G R, Adhikary B et al. A regional analysis of the fate and transport of mercury in East Asia and an assessment of major uncertainties. Atmospheric Environment, 2008, 42(6): 1144-1159.

[5] Pongprueksa P, Lin C-J, Lindberg SE et al. Scientific uncertainties in atmospheric mercury models III: Boundary and initial conditions, model grid resolution, and Hg (II) reduction mechanism. Atmospheric Environment, 2008, 42(8): 1828-1845.

[6] Monna F, Lancelot J, Croudace IW et al. Pb isotopic composition of airborne particulate material from France and the southern United Kingdom: Implications for Pb pollution sources in urban areas. Environmental Science & Technology, 1997, 31(8): 2277-2286.

[7] Wang Wan, Liu Xiande, Lu Yiqiang et al. Determination of isotope abundance ration of lead in Beijing atmospheric aerosol and lead source study. Journal of Chinese Mass Spectrometry Society, 2002, (1): 21-29.
[王琬, 刘咸德, 鲁毅强等. 北京冬季大气颗粒物中铅的同位素丰度比的测定和来源研究. 质谱学报, 2002, (1): 21-29..

[8] Sprovieri F, Pirrone N, Hedgecock IM et al. Intensive atmospheric mercury measurements at Terra Nova Bay in Antarctica during November and December 2000. Journal of Geophysical Research-Atmospheres, 2002, 107(D23).

[9] Temme C, Einax JW, Ebinghaus R et al. Measurements of atmospheric mercury species at a coastal site in the Antarctic and over the south Atlantic Ocean during polar summer. Environmental Science & Technology, 2003, 37(1): 22-31.

[10] Ebinghaus R, Kock H H, Temme C et al. Antarctic springtime depletion of atmospheric mercury. Environmental Science & Technology, 2002, 36(6): 1238-1244.

[11] Eneroth K, Holmen K, Berg T et al. Springtime depletion of tropospheric ozone, gaseous elemental mercury and non-methane hydrocarbons in the European Arctic, and its relation to atmospheric transport. Atmospheric Environment, 2007, 41(38): 8511-8526.

[12] Fitzgerald WF, Engstrom DR, Mason RP et al. The case for atmospheric mercury contamination in remote areas. Environmental Science & Technology, 1998, 32(1): 1-7.

[13] Steffen A, Douglas T, Amyot M et al. A synthesis of atmospheric mercury depletion event chemistry in the atmosphere and snow. Atmospheric Chemistry and Physics, 2008, 8(6): 1445-1482.

[14] Douglas T A, Sturm M, Simpson W R et al. Influence of snow and ice crystal formation and accumulation on mercury deposition to the Arctic. Environmental Science & Technology, 2008, 42(5): 1542-1551.

[15] Kellerhals M, Beauchamp S, Belzer W et al. Temporal and spatial variability of total gaseous mercury in Canada: results from the Canadian Atmospheric Mercury Measurement Network (CAMNet). Atmospheric Environment, 2003, 37(7): 1003-1011.

[16] Schroeder W H, Munthe J. Atmospheric mercury: An overview. Atmospheric Environment, 1998, 32(5): 809-822.

[17] Baker PGL, Brunke EG, Slemr F et al. Atmospheric mercury measurements at Cape Point, South Africa. Atmospheric Environment, 2002, 36(14): 2459-2465.

[18] Fu X, Feng X, Zhu W et al. Total gaseous mercury concentrations in ambient air in the eastern slope of Mt. Gongga, South-eastern fringe of the Tibetan Plateau, China. Atmospheric Environment, 2008, 42(5): 970-979.

[19] Wang Z W, Chen Z S, Duan N et al. Gaseous elemental mercury concentration in atmosphere at urban and remote sites in China. Journal of Environmental Sciences-China, 2007, 19(2): 176-180.

[20] Wang Junxia. Study on total gaseous mercury in the southern Tibetan Plateau
[D]. Lanzhou: Cold and arid Regions Environmental and Engineering Research Institute, Chinese Academy of Sciences, 2006.
[汪君霞. 青藏高原南部大气汞变化的研究
[D]. 兰州: 中国科学院寒区旱区环境与工程研究所, 2006..

[21] Bollhofer A, Rosman K J R. Isotopic source signatures for atmospheric lead: The Southern Hemisphere. Geochimicaet Cosmochimica Acta, 2000, 64(19): 3251-3262.

[22] Bollhofer A, Rosman K J R. Isotopic source signatures for atmospheric lead: The Northern Hemisphere. Geochimica et Cosmochimica Acta, 2001, 65(11): 1727-1740.

[23] Bollhofer A, Rosman K J R. The temporal stability in lead isotopic signatures at selected sites in the Southern and Northern Hemispheres. Geochimica et Cosmochimica Acta, 2002, 66(8): 1375-1386.

[24] Arimoto R, Schloesslin C, Davis D et al. Lead and mercury in aerosol particles collected over the South Pole during ISCAT-2000. Atmospheric Environment, 2004, 38(32): 5485-5491.

[25] Witt M, Baker A R, Jickells T D. Atmospheric trace metals over the Atlantic and South Indian Oceans: Investigation of metal concentrations and lead isotope ratios in coastal and remote marine aerosols. Atmospheric Environment, 2006, 40(28): 5435-5451.

[26] Cheng H R, Zhang G, Jiang J X et al. Organochlorine pesticides, polybrominated biphenyl ethers and lead isotopes during the spring time at the Waliguan Baseline Observatory, northwest China: Implication for long-range atmospheric transport. Atmospheric Environment, 2007, 41(22): 4734-4747.

[27] Shotyk W, Weiss D, Appleby P G et al. History of atmospheric lead deposition since 12, 370 C-14 yr BP from a peat bog, Jura Mountains, Switzerland. Science, 1998, 281(5383): 1635-1640.

[28] Hong S M, Candelone J P, Patterson C C et al. Greenland ice evidence of hemispheric lead pollution 2-millennia ago by Greek and Roman civilizations. Science, 1994, 265(5180): 1841-1843.

[29] Renberg I, Persson M W, Emteryd O. Preindustrial atmospheric lead contamination detected in Swedish lake-sediments. Nature, 1994, 368(6469): 323-326.

[30] Osterberg E, Mayewski P, Kreutz K et al. Ice core record of rising lead pollution in the North Pacific atmosphere. Geophysical Research Letters, 2008, 35(5).

[31] Dong Zhiwen, Li Zhongqin, Wang Feiteng et al. The pH and electrical conductivity of atmospheric environment from three shallow ice cores in the eastern Tianshan Mountains. Acta Geographica Sinica, 2009, 64(1): 107-116.
[董志文, 李忠勤, 王飞腾等. 天山东部冰芯pH值和电导率的大气环境空间差异. 地理学报, 2009 64(1): 107-116..

[32] Schuster P F, Krabbenhoft D P, Naftz D L et al. Atmospheric mercury deposition during the last 270 years: A glacial ice core record of natural and anthropogenic sources. Environmental Science & Technology, 2002, 36(11): 2303-2310.

[33] Vandal G M, Fitzgerald W F, Boutron C F et al. Variations in mercury deposition to Antarctica over the past 34,000 years. Nature, 1993, 362(6421): 621-623.

[34] Boutron C F, Vandal G M, Fitzgerald W F et al. A forty year record of mercury in central Greenland snow. Geophysical Research Letters, 1998, 25(17): 3315-3318.

[35] Boutron C F, Candelone J P, Hong S M. Past and recent changes in the large-scale tropospheric cycles of lead and other heavy-metals as documented in Antarctic and Greenland snow and ice: A review. Geochimica et Cosmochimica Acta, 1994, 58(15): 3217-3225.

[36] Boutron C F, Gorlach U, Candelone J P et al. Decrease in anthropogenic lead, cadmium and zinc in Greenland snows since the late 1960s. Nature, 1991, 353(6340): 153-156.

[37] Boutron C F. Historical reconstruction of the Earth's past atmospheric environment from Greenland and Antarctic snow and ice cores. Environmental Review, 1995, 3: 1-28.

[38] Schwikowski I, Barbante C, Doering T et al. Post-17th-century changes of European lead emissions recorded in high-altitude alpine snow and ice. Environmental Science & Technology, 2004, 38(4): 957-964.

[39] Li Zhen, Yao Tandong, Tian Lide et al. Atmospheric Pb variations in Central Asia since 1955 from Muztagata ice core record, eastern Pamirs. Chinese Science Bulletin, 2006, 51(16): 1996-2000.
[李真, 姚檀栋, 田立德等. 慕士塔格冰芯记录的近50 年来大气中铅含量变化. 科学通报, 2006, 51(15): 1833-1836..

[40] Lee K, Do Hur S, Hou S G et al. Atmospheric pollution for trace elements in the remote high-altitude atmosphere in central Asia as recorded in snow from Mt. Qomolangma (Everest) of the Himalayas. Sci. Total Environ., 2008, 404(1): 171-181.

[41] Rosman K J R, Chisholm W, Boutron C F et al. Lead isotopes and selected metals in ice from Law Dome, Antarctica. Annals of Glaciology, 1998, 27: 349-354.

[42] Van de Velde K, Vallelonga P, Candelone J P et al. Pb isotope record over one century in snow from Victoria Land, Antarctica. Earth and Planetary Science Letters, 2005, 232(1/2): 95-108.

[43] Rosman K J R, Ly C, Van de Velde K et al. A two century record of lead isotopes in high altitude Alpine snow and ice. Earth and Planetary Science Letters, 2000, 176(3/4): 413-424.

[44] Planchon F A M, van de Velde K, Rosman K J R et al. One hundred fifty-year record of lead isotopes in Antarctic snow from Coats Land. Geochimica et Cosmochimica Acta, 2003, 67(4): 693-708.

[45] Bindler R, Renberg I, Appleby P G et al. Mercury accumulation rates and spatial patterns in lake sediments from west Greenland: A coast to ice margin transect. Environmental Science & Technology, 2001, 35(9): 1736-1741.

[46] Fitzgerald W F, Engstrom D R, Lamborg C H et al. Modern and historic atmospheric mercury fluxes in northern Alaska: Global sources and Arctic depletion. Environmental Science & Technology, 2005, 39(2): 557-568.

[47] Biester H, Bindler R, Martinez-Cortizas A et al. Modeling the past atmospheric deposition of mercury using natural archives. Environmental Science & Technology, 2007, 41(14): 4851-4860.

[48] Lorey P, Driscoll C T. Historical trends of mercury deposition in Adirondack lakes. Environmental Science & Technology, 1999, 33(5): 718-722.

[49] Lockhart W L, Wilkinson P, Billeck B N et al. Current and historical inputs of mercury to high-latitude lakes in Canada and to Hudson Bay. Water, Air, & Soil Pollution, 1995, 80(1): 603-610.

[50] Yang H D, Rose N L, Battarbee R W et al. Mercury and lead budgets for Lochnagar, a Scottish mountain lake and its catchment. Environmental Science & Technology, 2002, 36(7): 1383-1388.

[51] Sanders R D, Coale K H, Gill G A et al. Recent increase in atmospheric deposition of mercury to California aquatic systems inferred from a 300-year geochronological assessment of lake sediments. Applied Geochemistry, 2008, 23(3): 399-407.

[52] Swain E B, Engstrom D R, Brigham M E et al. Increasing rates of atmospheric mercury deposition in Midcontinental North America. Science, 1992, 257: 784-787.

[53] Farmer J G, Eades L J, Mackenzie A B et al. Stable lead isotope record of lead pollution in Loch Lomond sediments since 1630 AD. Environmental Science & Technology, 1996, 30(10): 3080-3083.

[54] Renberg I, Brannvall M L, Bindler R et al. Stable lead isotopes and lake sediments: A useful combination for the study of atmospheric lead pollution history. Science of the Total Environment, 2002, 292(1/2): 45-54.

[55] Ndzangou S O, Richer-Lafleche M, Houle D. Sources and evolution of anthropogenic lead in dated sediments from Lake Clair, Quebec, Canada. Journal of Environmental Quality, 2005, 34(3): 1016-1025.

[56] Lindeberg C, Bindler R, Renberg I et al. Natural fluctuations of mercury and lead in Greenland lake sediments. Environmental Science & Technology, 2006, 40(1): 90-95.

[57] Su Qiuke, Qi Shihua, Jiang Jingye et al. Environmental geochemistry assessment of mercury from lakes in Wuhan City, Hubei Province, China. Geochemica, 2006, 35(3): 265-270.
[苏秋克, 祁士华, 蒋敬业等. 武汉城市湖泊汞的环境地球化学评价. 地球化学, 2006, 35(3): 265-270..

[58] Liu E F, Shen J, Liu X Q et al. Variation characteristics of heavy metals and nutrients in the core sediments of Taihu Lake and their pollution history. Science in China: Series D, 2006, 49: 82-91.

[59] Yao Shuchun, Xue Bin, Zhu Yuxin et al. Sediment lead pollution records from lakes at the middle and lower reaches of Changjiang river basin: Case study in Honghu, Guchenghu, and Taihu lakes. Quaternary Sciences. 2008, 28(4): 659-666.
[姚书春, 薛滨, 朱育新等. 长江中下游湖泊沉积物铅污染记录: 以洪湖、固城湖和太湖为例. 第四纪研究, 2008, 28(4): 659-666..

[60] Chen Jing'an, Wan Guojiang, Huang Guirong. Geochemical phases and pollution history of heavy metals in sediments of Erhai. Geology-Geochemistry, 1998, 26(2): 1-8.
[陈敬安, 万国江, 黄荣贵. 洱海沉积物重金属地球化学相及其污染历史研究. 地质地球化学, 1998, 26(2): 1-8..

[61] Lee C S L, Qi S H, Zhang G et al. Seven thousand years of records on the mining and utilization of metals from lake sediments in central China. Environmental Science & Technology, 2008, 42(13): 4732-4738.

[62] Xiao Cunde, Qin Dahe, Yao Tandong et al. The global pollution revealed by Pb, Cd in the surface snow of Antarctic, Arctic and Qinghai-Xizang Plateau. Chinese Science Bulletin, 1999, 44(23): 2558-2563.
[效存德, 秦大河, 姚檀栋等. 南, 北极和青藏高原现代降水中Pb, Cd 反映的全球大气污染. 科学通报, 1999, 44(23): 2558-2563..

[63] Huo Wenmian, Yao Tandong, Li Yuefang. Increasing atmospheric pollution revealed by Pb record of a 7000-m ice core. Chinese Science Bulletin, 1999, 44(14): 1309-1312.
[霍文冕, 姚檀栋, 李月芳. 7000m 处冰芯中Pb 记录揭示人类活动污染在加剧. 科学通报, 1999, 44(9): 978-981..

[64] Cong Z Y, Kang S C, Smirnov A et al. Aerosol optical properties at Nam Co, a remote site in central Tibetan Plateau. Atmospheric Research, 2009, 92(1): 42-48.

[65] Xie Manping, Zhu Liping, Peng Ping et al. Ostracodes assemblages and their environmental significance from lake core of Nam Co, Tibetan Plateau. Acta Geographica Sinica, 2008, 63(9): 931-944.
[谢曼平, 朱立平, 彭萍等. 8.4 ka 以来纳木错湖芯介形类组合的环境变化意义. 地理学报, 2008, 63(9): 931-944..

[66] Li M, Kang S, Zhu L et al. Mineralogy and geochemistry of the Holocene lacustrine sediments in Nam Co, Tibet. Quaternary International, 2008, 187(1): 105-116.

[67] Kang S, Qin D, Ren J et al. Annual accumulation in the Mt. nyainqentanglha ice core, southern Tibetan Plateau, China: Relationships to atmospheric circulation over Asia. Arctic Antarctic and Alpine Research, 2007, 39: 663-670.

Modern Process and Historical Reconstruction of Pb and Hg in Remote Areas: A Critical Review

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